"The Australian Government is interested in developing a hydrogen
export industry to export our abundant renewable energy," said Professor
O'Mullane from QUT's Science and Engineering Faculty.
"In principle, hydrogen offers a way to store clean energy at a scale
that is required to make the rollout of large-scale solar and wind
farms as well as the export of green energy viable.
"However, current methods that use carbon sources to produce hydrogen
emit carbon dioxide, a greenhouse gas that mitigates the benefits of
using renewable energy from the sun and wind.
"Electrochemical water splitting driven by electricity sourced from
renewable energy technology has been identified as one of the most
sustainable methods of producing high-purity hydrogen."
Professor O'Mullane said the new composite material he and PhD
student Ummul Sultana had developed enabled electrochemical water
splitting into hydrogen and oxygen using cheap and readily available
elements as catalysts.
"Traditionally, catalysts for splitting water involve expensive
precious metals such as iridium oxide, ruthenium oxide and platinum," he
said.
"An additional problem has been stability, especially for the oxygen evolution part of the process.
"What we have found is that we can use two earth-abundant cheaper
alternatives -- cobalt and nickel oxide with only a fraction of gold
nanoparticles -- to create a stable bi-functional catalyst to split
water and produce hydrogen without emissions.
"From an industry point of view, it makes a lot of sense to use one
catalyst material instead of two different catalysts to produce hydrogen
from water."
Professor O'Mullane said the stored hydrogen could then be used in fuel cells.
"Fuel cells are a mature technology, already being rolled out in many
makes of vehicle. They use hydrogen and oxygen as fuels to generate
electricity -- essentially the opposite of water splitting.
"With a lot of cheaply 'made' hydrogen we can feed fuel
cell-generated electricity back into the grid when required during peak
demand or power our transportation system and the only thing emitted is
water."
Source: https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201804361
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